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MATERIAL SAFETY DATA Revision: Effective: 1197211 SHEET

Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts Store container on their side so that the filling bungs are under the fluid level. OTHER EFFECTS: An oil film may cause physical damage to organisms and disturb the transportation of oxygen in the intermediate zone

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4. FIRST AID MEASURES

On contact with acids most dithiophosphate acid esters and salts produce the toxic compound hydrogen sulfide (rotten egg gas). No specific toxicological data found for the sodium salt of mercaptobenzothiazole, however mercaptobenzothiazole itself has been known to cause skin sensitisation in test guinea pigs. It is corrosive to both skin and eyes. 12.

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SAFETY DATA SHEET

Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts 68649-42-3 1 - 3 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. FIR No.: 183455 SDS US

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SAFETY DATA SHEET

Phosphorodithioic Acid O,o-bis(2-ethylhexyl) Ester, Zinc Salt (CAS 4259-15-8) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire

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Page 1/9 Safety data sheet complying with Regulation 1907

Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts Eye Dam. 1, H318; Aquatic Chronic 2, H411; Skin Irrit. 2, H315 1-2.5% CAS: 70024-69-0 EINECS: 274-263-7 Reg.nr.: 01-2119492616-28-ΧΧΧΧ Benzenesulfonic acid, mono-C16-24-alkyl derivs., calcium salts Skin Sens. 1B, H317 0.3-1% CAS: 121158-58-5 EC number: 310-154-3

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088157 GREASE EP 2

Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts Most important symptoms and effects, both acute and delayed Eye contact Not classified based on available data. The supplier of some components contained within ABC powder. Foam. Water spray or fog.

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US4283338A

Disclosed is a method for improving the yield of dialkyl dithiophosphoric acid esters produced by the Lewis acid catalyzed reaction of an O,O-dialkyl dithiophosphoric acid and an organic chloride. More specifically, the method concerns the improvement wherein the reaction is conducted under sufficient pressure to maintain the liberated hydrogen chloride in the reaction system during the course

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Phosphorodithioic acid, O,O

H314 (): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation] Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard

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Phosphorodithioic acid, O,O

Therefore,LC50 was considered to be5,000 mg/m 3 when rats were exposed with Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts by inhalation. Information on Registered Substances comes from registration dossiers which have been assigned a registration number.

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Phosphorodithioic acid, O,O

Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts 68649-42-3 Suppliers,provide Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts 68649-42-3 product and the products related with China (Mainland) Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts 68649-42-3 Henan Tianfu Chemical Co., Ltd. China (Mainland)

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MULTIS COMPLEX EP 2

effects Short term, local effectsLong term, systemic effects Long term, local effects Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts*** 68457-79-4 5.93 mg/kg bw/day Dermal 2.06 mg/m Inhalation 0.24 mg/kg bw/day Oral Reaction products of 4-methyl-2-pentanol and diphosphorus pentasulfide, propoxylated, esterified

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EC safety data sheet

EC safety data sheet 6page: 5(6) sensitising to skin. Experience in practice Repeated and prolonged skin contact may cause removal of natural fat from the skin and irritation of the skin. Eye contact with the product may cause slight irritation. Inhalation of vapours from the heated product can cause irritation of the respiratory tract and the eyes.

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SAFETY DATA SHEET

• Dry Chemical Powder • CO 2 • Foam Do not use water jets. Use water spray to cool fire exposed containers. Hazards from Combustion Products : Product is a mobile liquid. Incompatible with strong oxidising agents, acids/alkalis. Combustion may produce oxides of carbon, nitrogen and sulphur,

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ZIC X7 5W

Carbon dioxide, extinguishing powder, foam, fog sprays, water jets. Unsuitable extinguishing substances: Unknown. Products of combustion: Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Water. May form toxic mixtures in air and may accumulate in sumps, pits and other low-lying

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Phosphorodithioic acid, O,O

Precautionary statements - describe recommended measures to minimise or prevent adverse effects resulting from exposure to a hazardous product or improper storage or handling of a hazardous product. Guidance on safe use - recommendations by substance registrant on the proper use of the substance in various situations.

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Safety data sheet

CO2, powder or water spray. Fight larger fires with water spray. Keep people at a distance and stay on the windward side. diatomite, acid binders, universal binders, sawdust). 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment.

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Phosphorodithioic acid, O,O

Classification of Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts for effects in the environment: The chemical Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (CAS no. 67649-42-3) is used in as a corrosion inhibitor in lubricants.

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QUARTZ INEO MC3 5W

effects Short term, local effectsLong term, systemic effects Long term, local effects Materials to Avoid Oxidizing agents, Acids. Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts 84605-29-8 8.31 mg/m Inhalation 12.1 mg/kg Dermal 8.1. Control parameters Phenol, dodecyl-, branched 121158-58-5 166 mg/kg bw/day Dermal

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1. Identification of Substance Company

Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts 84605-29-8 1% This is a commercial product whose exact ratio of components may vary. Trace quantities of impurities are also likely. 4. First Aid General Information

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SAFETY DATA SHEET

May cause long lasting harmful effects to aquatic life. Injection of pressurized hydrocarbons can cause severe permanent tissue damage. Initial symptoms may be minor. Hazard pictograms : Precautionary statements Prevention :Wear eye or face protection. Avoid release to the environment. Wash hands thoroughly after handling.

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SAFETY DATA SHEET

symptoms/effects, acute and delayed Direct contact with eyes may cause temporary irritation. 5. Fire-fighting measures Suitable extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide or dry powder. Unsuitable extinguishing media Do not use water. Will float on water and can be re-ignited. Specific hazards arising from the chemical

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MULTIS COMPLEX HV 2

Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts 68457-79-4 LD50 3600 mg/kg (Rat - OECD 401)LD50 20000 mg/kg (Rabbit - OECD 402) Information on toxicological effects Symptoms Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Skin contact Not classified. High pressure injection of the products under the skin may have very serious

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ATLANTA MARINE D 3005

ATLANTA MARINE D 3005 Version 1 Not classified. Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts Mutagenicity This product is not classified as mutagenic. - 3160 mg/kg ( Rabbit ) Ingestion Reproductive toxicity This product does not contain any known or suspected reproductive hazards. Not classified.

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SAFETY DATA SHEET

symptoms/effects, acute and delayed May be mildly irritating to skin, eyes and respiratory system. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms may include stinging and tearing. Symptoms may include upper respiratory irritation, coughing, and breathing difficulties. Ingestion

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RUBIA WORKS 1000 15W

effects Long term, local effects Phosphorodithioic acid, mixed O,O-bis(sec-Bu and 1,3-dimethylbutyl) esters, zinc salts*** 68784-31-6 4.8 mg/kg bw/day (dermal) 1.67 mg/m3 (inhalation) 0.19 mg/kg bw/day (oral) Predicted No Effect Concentration (PNEC) *** Chemical NameWater Sediment Soil Air STP Oral Phosphorodithioic acid, mixed O,O-bis(sec-Bu and 1,3-dimethylbutyl)

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Safety data sheet according to Regulation (EC) No 1907

4.2 Most important symptoms and effects, both acute and delayed If applicable delayed symptoms and effects can be found in section 11 and the absorption route in section 4.1. With long-term contact: Nausea Dizziness Product removes fat. Drying of the skin. Dermatitis (skin inflammation) Ingestion: Vomiting Danger of aspiration. Oedema of the lungs

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Acephate (Acetylphosphoramidothioic acid O,S-dimethyl ester) Acifluorfen, sodium salt [5-(2-Chloro-4-(trifluoromethyl)phenoxy)-2-nitrobenzoic acid, sodium salt] Ammonia (includes anhydrous ammonia and aqueous ammonia from water dissociable ammonium salts and other sources; 10 percent of total aqueous ammonia is reportable under this listing

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MULTIS EP 2

Phosphorodithioic acid, mixed O,O-bis(iso-Bu and pentyl) esters, zinc salts 68457-79-4 LD50 3600 mg/kg (Rat - OECD 401)LD50 20000 mg/kg (Rabbit - OECD 402) Information on toxicological effects Symptoms Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Skin contact Not classified. High pressure injection of the products under the skin may have very serious

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SAFETY DATA SHEET ROYCO LGF (YELLOW)

Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (Component ) : Result: Irritating to skin. 2,6-di-tert-butyl-p-cresol (Component ) : Species: Rabbit Result: No skin irritation Eye irritation (Product ) : Remarks: Irritating to eyes. Sensitisation Phosphorodithioic acid, O,O

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1. Identification of Substance Company

Phosphorodithioic acid, mixed O,O-bis(1,3-dimethylbutyl and iso-Pr) esters, zinc salts 84605-29-8 1% This is a commercial product whose exact ratio of components may vary. Trace quantities of impurities are also likely. 4. First Aid General Information

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